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GCSE Chemistry Revision

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GCSE Chemistry revision

Atoms, elements and compounds

A simple model of the atom, symbols, relative atomic mass, electronic charge and isotopes

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Key knowledge

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Structure of an Atom

  • An atom consists of a central nucleus containing protons and neutrons, with electrons orbiting the nucleus.
  • Hydrogen is the simplest element, with just one proton in its nucleus and one electron orbiting it.
  • Helium is the next smallest element, with two protons and two neutrons in the nucleus and two electrons orbiting it.

The Periodic Table

  • There are around 100 different elements, all organised into the periodic table where each box represents a different element.
  • Each element is represented by a nuclear symbol, which includes a one- or two-letter symbol, the atomic number, and the mass number.
  • Some element symbols are not obvious from their names — for example, sodium is Na and iron is Fe.

Atomic Number

  • The atomic number is the number of protons in the nucleus of an atom and is unique to each element.
  • Any atom with a given number of protons must be the element that corresponds to that atomic number — for example, any atom with six protons is carbon.
  • If an atom has three protons, the periodic table tells us it must be lithium, which has an atomic number of three.

What Are Isotopes?

  • Isotopes are different forms of the same element that have the same number of protons but a different number of neutrons.
  • The number of neutrons in an atom can vary without changing which element it is, as long as the number of protons stays the same.
  • Because isotopes only differ in the number of neutrons, they behave in almost identical ways chemically.

Isotopes of Carbon

  • Carbon-12, the most common form of carbon, has six protons, six neutrons, and six electrons, giving it a mass number of 12.
  • Carbon-13 is a rarer isotope that still has six protons and six electrons, but has seven neutrons, giving it a mass number of 13.
  • The mass number of an isotope is the total number of protons and neutrons in its nucleus.

Isotopic Abundance

  • Isotopic abundance refers to how common or rare a particular isotope is within a sample of an element, usually expressed as a percentage.
  • Copper has two stable isotopes: copper-63 with an abundance of 69.2% and copper-65 with an abundance of 30.8%.
  • The abundances of all isotopes of an element must add up to 100%, as they account for all atoms of that element.

Calculating Relative Atomic Mass

  • The relative atomic mass (Aᵣ) is the average mass of all the isotopes of an element, taking into account their relative abundances.
  • The formula for relative atomic mass is: Aᵣ = (Σ(isotope abundance × isotope mass) / Σ(abundances of all isotopes))
  • For copper, the calculation is ((69.2 × 63) + (30.8 × 65) / 69.2 + 30.8) = (6361.6 / 100) = 63.6 (to one decimal place).
  • The relative atomic mass of copper is 63.6, meaning the average mass of a copper atom is 63.6 atomic mass units.