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GCSE Chemistry Revision
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GCSE Chemistry revision
Cells and batteries
Chemical cells and fuel cells (chemistry only)
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Key knowledge
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Relative Reactivity and Ion Formation via Displacement
- Tendency to Form Positive Ions: A metal's reactivity is determined by how easily its atoms lose outer electrons to form positive ions (cations), with more reactive metals displacing less reactive metals from solutions of their aqueous ions.
- Displacement Examples: In the series Mg > Zn > Fe > Cu > Ag, magnesium has the greatest tendency to form positive ions. Adding magnesium ribbon to copper(II) sulfate solution results in a displacement reaction where magnesium dissolves and copper metal coats the surface: Mg(s) + Cu²⁺(aq) → Mg²⁺(aq) + Cu(s)
- Conversely, adding copper metal to silver nitrate solution displaces silver, but copper cannot displace iron or magnesium ions because copper is less reactive.
Simple Cells
- Connecting two different metals in an electrolyte creates a chemical cell, where a greater difference in reactivity between the two metals generates a higher voltage output.
- Example: A cell made with a Magnesium-Copper electrode pair produces a significantly higher voltage than an Iron-Copper pair because magnesium loses electrons far more readily than iron; however, cells must be evaluated practically based on voltage needs, material costs, and electrode corrosion over time.