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GCSE Chemistry Revision

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GCSE Chemistry revision

Metals and non-metals

The periodic table

AQA 4.1.2.3 Foundation & Higher
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Key knowledge

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Position of Metals and Non-Metals on the Periodic Table

  • Most elements are metals, and they are found towards the bottom-left of the periodic table, whilst non-metals are found towards the top-right.
  • Metals form positive ions when they react (e.g. calcium forms Ca²⁺), whereas non-metals either form negative ions (e.g. chloride, Cl) or do not form ions at all (e.g. carbon).

Electron Arrangements and Ion Formation

  • Atoms are stable when they have a full outer shell of electrons, which drives them to either lose or gain electrons during reactions.
  • Metals on the left of the periodic table have few electrons in their outer shell (e.g. calcium in Group 2 has 2 electrons), making it easy to lose them and form positive ions.
  • Non-metals like chlorine have 7 outer electrons, so losing all of them to form a positive ion would require too much energy — instead they gain electrons to form negative ions.

Why Reactivity Increases Down a Group for Metals

  • Elements further down the periodic table have more electron shells (e.g. lead has 6 shells), placing the outer electrons much further from the nucleus.
  • The greater the distance between the outer electrons and the positive nucleus, the weaker the attraction holding those electrons in place.
  • This means metals lower in a group lose their outer electrons more easily during reactions, making them more reactive.

Physical Properties of Metals

  • Metals have metallic bonding, a strong type of bonding unique to metals that is responsible for their characteristic physical properties.
  • Metals are malleable, meaning they can be bent or hammered into shape without snapping.
  • Metals are excellent conductors of heat and electricity, which is why they are used in electrical wiring.
  • Nearly all metals have high melting and boiling points, with some remaining solid even above 2,000°C.
  • Additional properties of metals include being shiny and sonorous, meaning they produce a ringing sound when struck.

Physical Properties of Non-Metals

  • Non-metals tend to be dull in colour and brittle, meaning they break easily (e.g. the carbon in a pencil).
  • Non-metals generally have low melting and boiling points, and many exist as gases at room temperature.
  • Non-metals are poor conductors of electricity and typically have lower densities than metals, meaning they weigh less for a given volume.

Introduction to Transition Metals

  • Transition metals are found in the centre block of the periodic table and display all the typical properties of metals described above.
  • A key feature of transition metals is that they can form more than one type of ion; for example, chromium can form 2+, 3+, and 6+ ions.
  • Transition metal ions are often coloured in aqueous solution; for example, copper(II) ions are blue, iron(II) ions are green, and chromium(VI) ions are orange.

Transition Metals as Catalysts

  • A catalyst is a substance that increases the rate of a chemical reaction without being used up itself.
  • Iron acts as a catalyst in the Haber process, which is used to manufacture ammonia.
  • Nickel is used as a catalyst in the hydrogenation of alkenes, a process used to produce margarine.